The National Electric Code is not provided and must be consulted elsewhere. All rights reserved. For Acrylonitrile service, the seal gasket elastomer should be silicone rubber. All rights reserved. However, if administered effectively, commercially available antidotes can preclude serious harm. All diagrams in Appendix 3.1 are included courtesy of the American Petroleum Institute; publication #RP 500, Recommended Practice for Classification of Locations for Electrical Installations at Petroleum Facilities. firstname.lastname@example.org 800-424-9300 CHEMTREC, SAFETY DATA SHEET. Steam cleaning can damage commonly-used floating roof seal materials. Product and company identification Trade name of product Product use Product dilution information : OASIS PRO 10 HEAVY DUTY ALL PURPOSE, Februar, 2014 Technical Data Sheet PLA Polylactide Cas No. Additionally, long term exposure to Acrylonitrile has been shown to cause cancer in laboratory animals. Care must be exercised in determining sufficient fire fighting ability when confronting an incident. White paint is recommended for the exterior surface to minimize interior temperature increases. Methanex Corporation assumes no liability whatsoever with should be eliminated in areas generating unavoidable vapors, or where accidental vapor releases are highly probable. Next, consult an accepted electric code which lists suitable equipment for use in that area classification. Important physical property data are listed in Table 2.1. MATERIAL SAFETY DATA SHEET 1. Identification of the substance/preparation and company/undertaking, SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION. Closed systems should be used for drawing product samples. 129 Lockwood St. 1-800-255-3924-CHEM-TEL (24 hour), MATERIAL SAFETY DATA SHEET DATE: 2009, revised July 2011 PRODUCT NAME: BOSTON BRAKE & PARTS CLEANER PRODUCT CODE: 78200. : 514122, 514123 DRY CIDER VINEGAR SDS DATE: 05/05/15. For a partial list of these limits, see Table 6.1 Sample of Acrylonitrile occupational exposure limits. J. Amer. 10 ppm, Ceiling (complete 10 ppm, Ceiling; IDLH 85 ppm (Immediately explanation NIOSH-REL 1 ppm; Ca occupational carcinogen, Skin. 0000001518 00000 n Before handling, always consult a current Materials Safety Data Sheet (MSDS), available from INEOS, for information on the chemical. 1272/2008 Section 1. ACGIH-TLV The American Conference of Governmental Industrial Hygienists (ACGIH) has established 2 ppm as the Threshold Limit Value (TLV) for an eight (8) hour time-weighted average. 0 SafetyTac¨ Inline Printed Floor Marking Tape provides the ability to outline an area with a repeating sign and a clear demarcation of where that marking is applicable. 1 Acrylonitrile Safe Storage and Handling Guide 2 Table of Contents Introduction 1.0 Physical, chemical and thermodynamic properties 2.0 Storage 3.0 Transfer and transport 4.0 Fire safety 5.0 Occupational safety and health 6.0 Medical response and first aid 7.0 Emergency response and environmental protection 8.0 trailer Facilities and equipment must be diligently maintained and properly used. Phys., 1952, 20, Vogel, A.I.,Cresswell, W.T., Jeffery,C.H., Leicester, J. J.Chem. Tanks must be located away from a potential source of ignition, including the possibility of radiation from a fire in an adjacent area. In no case, however, should the interval between inspections exceed 20 years. Informing consumers and those involved in the handling of the product on its properties and functionality. A manhole, or manway, of at least 20 should be provided on all tanks to allow for internal inspection and cleaning. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATHESON TRI-GAS, INC. Training is essential to reduce the possibility of the following hazards: flame propagation from vessel to shore systems; over or under pressurization; and chemical spillage. The solubilities of Acrylonitrile in water and water in Acrylonitrile as a function of temperature are summarized in Figure 2.5. However, this may not be effective if the container is insulated. The pump mechanical seals can be of either the single, double or tandem seal design. 3. PRODUCT AND COMPANY INFORMATION SECTION 1 Company Identification Name: Becton Dickinson Medical Systems Address: 9450 South State Street Sandy, UT 84070 FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE. The source of vapor shall be the operating envelope and stored position of the outboard flange connection of the loading arm (or hose). Tank Location The arrangement of tanks and equipment should take into account access for normal operation and maintenance, emergency response teams and equipment, as well as emergency evacuation. The resistance to ground at any point of the installation should be less than 10 ohms. 25 feet horizontally in all directions on the pier side from that portion of the hull containing cargo tanks. Acrylonitrile and water are partly soluble in each other. IDENTIFICATION Product Name Recommended use of the chemical and restrictions on use Identified uses Tape for industrial use Company Identification Customer Information Number Emergency, SECTION 1 - PRODUCT IDENTIFICATION / PREPARATION INFORMATION Product Information Trade name : Product code : 638853 385 Supplier : Tremco Canada division 220 Wicksteed Avenue Toronto, ON M4H 1G7 Telephone, Material Safety Data Sheet 1. Styrene Monomer: Safe Handling Guide July 2018. Sources of heat should also be avoided, including pumping Acrylonitrile against a closed valve to unusually high pressures or for unusually long periods of time. The odor threshold is also above the 10 ppm Ceiling Limit. Opening a gauge hatch is not recommended where it might involve personal exposure to Acrylonitrile. Mixture, EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours), SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING. See Section 3.) Nitrogen blanketing substantially reduces the potential for flammability of vapors above the surface of liquid Acrylonitrile. Chem., 1951, 43, Pagerey, P.F., St. Clair, C.R., Sibbitt, W.L. Level indicators should be intrinsically safe for use with Acrylonitrile, based on nationally-accepted standards. Source: Reference 15 The values for above properties are listed in Table 2.1. Monitoring to evaluate a worker s eight (8) hour exposure potential is performed using NIOSH Method 1604, issue 2 dated August 15, To perform this method, Table 6.2: Monitoring requirements Action Level = 1 ppm (in the United States) Permissible Exposure Limit = 2 ppm ( in the United States) Monitor results Below the Action Level At or below the Action Level, but below the Permissible Exposure Limit Monitoring frequency Monitoring may be discontinued for that employee. The international designation for Acrylonitrile is CAS No , assigned by the Chemical Abstracts Service. Emergency Contact: 150 Allen Road Suite 302 CHEMTREC 1-800-424-9300 Basking Ridge, New Jersey, Page n.1 / 5 Safety Data Sheet 1. Electric pumps should be flameproof. Its chemical formula is CH 3OH. Chem., 1954, 22, Hall, H.K., Jr., Baldt, J.H. 1.2 The contents of each cylinder and container must be clearly identified (by tag or stamp) on the cylinder. 2. The BLCH Guide provides guidance on the various solutions available to achieve an international level of consistency for safe and high quality operation of bulk liquid chemical terminals and the handling of liquid chemicals in bulk in the associated transport and distribution sectors. Reviews and General Articles 1. The chemical must not contact an open flame. During ammoxidation, propylene, ammonia and air are fed through a catalyst at a high temperature. Clear glass should not be used if prolonged exposure to light is expected. 7664-93-9 >94.19 % WT >94.19 % VOL SARA 313 NO, Material Safety Data Sheet Ampicillin, sodium salt MSDS, MATERIAL SAFETY DATA SHEET WWF -20 1 of 5 1 Gal Xtreme Blue -20 Windshield Washer Fluid. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Figure 2.8 shows the solubility of oxygen in Acrylonitrile, expressed in parts per million, at several temperatures when Acrylonitrile is in equilibrium with air under a normal pressure of 1 atmosphere. 3.8, 17 Appendix 3.2 The following diagrams illustrate the recommended construction of Acrylonitrile load and unload terminals for truck, rail, ISO tank, and marine. Tank diameter manway, 20 Table 3.2: Recommended manway sizes Internal pipework should be designed to prevent splash filling. 11 The floor of the diked area should slope away from tanks to prevent minor spills from collecting and remaining underneath a tank. VICTOR Material Safety Data Sheet SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Product Name: Liquefied Petroleum Gas or Propane (0916-0004) (0056-1297) Product Use: Heating Fuel Synonyms: Propane, LP-Gas, Product Code: Product Name: Product Use: Manufacturer Information Company Name: SAFETY DATA SHEET 1. Product and Company Identification 60-5200-xx Glen-Pak TM DNA purification cartridge For Research Use. Acrylonitrile storage tanks normally do not require insulation or refrigeration. * * * EMERGENCY OVERVIEW * * * High pressure gas. Contact with these chemicals can cause a chemical reaction resulting in a fire or explosion. Extinguishment Acrylonitrile fires may be extinguished with: Foam AFFF - (aqueous film forming foam) that is alcohol resistant is recommended for extinguishing polar solvents such as Acrylonitrile. at 70 o F, or 104 psi. Acrylonitrile is reactive with, and must be kept away from, strong oxidizers, especially bromine. Pressure buildup can be alleviated by venting the tank through an adequate pressure relief-vent system. From the water level to 25 feet above the cargo tanks at their highest position 3. Seal face materials should be carbon against silicon carbide or carbon against tungsten carbide. For advanced or massive fire, fire fighting should be done from a safe distance or protected location. Technical and safety information is available from INEOS. The arm or hose will have a top inlet with a control valve to ensure that it is self-draining after use. Chemical product and company identification Physical, Safety Data Sheet Issue Date: 26-Nov-2013 Revision Date: 01-Jan-2015 Version B Product Identifier Product Name Other means of identification SDS # Other Information 1. 0000049895 00000 n 3. The nitrile group can undergo hydrogenation, hydrolysis, hydration, esterification, cyclization and reduction. Trade name of product Product use Code Date of issue Product and company identification Product dilution information STAINLESS STEEL CLEANER, MATERIAL SAFETY DATA SHEET SECTION 1 -- CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME Sav-A-Hoof Protectant PRODUCT CODE 309 ISSUE DATE 11/15/14 EMERGENCY TELEPHONE NUMBERS DISTRIBUTOR SBS EQUINE. PRODUCT IDENTIFICATION PRODUCT NAME: CHEMICAL NAME: Nitrogen, compressed Nitrogen FORMULA: N 2 SYNONYMS: Nitrogen gas, Gaseous Nitrogen, GAN August 1997 MANUFACTURER: Ferrellgas Material Safety Data Sheet - Propane Ferrellgas One Liberty Plaza Liberty, MO 64068 Section 1: Emergency Information 24 Hour Emergency Number Call 1-800-424-9300 (Chemtrec) in case of emergencies, PRODUCT AND COMPANY INFORMATION SECTION 1 Manufacturer/Distributor Product Name: Synonyms: Intended Use: Water-Jel Technologies 50 Broad Street Carlstadt, NJ 07072 201-507-8300 800-275-3433 Burn Jel Burn, SECTION 1: IDENTIFICATION Safety Data Sheet for Whole Grain PRODUCT NAME: SDS NUMBER: WHOLE GRAIN GRAIN SYNONYMS/OTHER MEANS OF IDENTIFICATION: INTENDED USE: FOOD MANUFACTURER: (company name) EMERGENCY, Standard Operating Procedure FLAMMABLE LIQUIDS This standard operating procedure (SOP) is intended to provide general guidance on how to safely work with flammable liquids. Hoses should be frequently inspected for wear or damage, and replaced as necessary. Therefore, the maximum concentration of Acrylonitrile exposure allowed over an eight (8) hour workday is 2 ppm. In the U.S. all tanks should be surrounded by a dike wall capable of containing 110 percent of the largest tank within the dike. It is miscible with water, The rinse water should then be drained into a suitable water treatment system. Tank roofs should be fixed, with or without an internal floating roof. 1.1, 4 Section 2: Physical, Chemical and Thermodynamic Properties Acrylonitrile is a clear, colorless liquid with a slightly pungent odor. 4.1, 22 Truck and Rail Safety Routine inspections should be performed before each load of Acrylonitrile is loaded into an ISO tank container, bulk truck or rail car. SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Product identifier/trade name: Product code/internal Identification: Product use/description: Supplier identifier: Manufactured for: Emergency phone number: SECTION 1: Identification Safety Data Sheet SOMAmer Reagent 1.1 Product identifier Product name SOMAmer Reagent (aptamer) 1.2 Supplier s details Name Address Email SomaLogic, Inc. 2945 Wilderness Place, SOLVENT CLEANER MSDS Page 1 of 5 SAFETY DATA SHEET (To comply with OSHA s Hazard Communication Standard 29CFR 1910.1200/ANSI z400.1-1993) 1. Internal Inspection Corrosion rates measured during previous inspections or experience with tanks in similar service should be considered in determining the intervals between internal inspections. Fires involving Acrylonitrile can release toxic gases such as hydrogen cyanide, oxides of nitrogen or carbon monoxide. Identification of the substance Identification of the product Product name : Hydrogen peroxide solution 60% Manufacturer / supplier identification Company : A.Ş. The vapors of Acrylonitrile, if inhaled at certain concentrations, can produce serious acute (short-term) toxicity, including loss of consciousness or death. Abbreviations CD = Chemical drain LI = Level indicator TI = Temperature indicator LAH = Level alarm high S/D = Shut down O2 = Oxygen FO = Fail open Figure A-2a: Acrylonitrile barge loading Figure A-2b: Acrylonitrile barge unloading 3.9, 18 Figure A-2c: Acrylonitrile railcar loading Figure A-2d: Acrylonitrile railcar unloading 3.10, 19 Figure A-2e: Acrylonitrile Iso-truck loading Figure A-2f: Acrylonitrile Iso-truck unloading 3.11, 20 Figure A-2g: Acrylonitrile truck loading Figure A-2h: Acrylonitrile truck unloading 3.12, 21 Section 4: Transfer and Transport Equipment and procedures for transfer and transport of Acrylonitrile will vary widely depending on prevailing national and local operating regulations. When designing a storage facility consider the optimum storage capacity keeping in mind the expected delivery vehicle and quantity, and estimated future capacity requirements. Vapor mixtures of Acrylonitrile and air containing between 3 and 17 percent Acrylonitrile are potentially flammable (see flammability limits in Table 2.1) This flammability envelope is a function of temperature, pressure and the concentration of oxygen in the vapor. The isolation valve should be closed and locked when not in use. Assure that Acrylonitrile is efficiently condensed and that the condensed Acrylonitrile is properly inhibited. 1. Working areas, for example, tank stairs, platforms, loading and unloading points, should be adequately illuminated during working hours. 3.3, 12 Scheduled inspection All tanks should be given a formal visual external inspection at least every 5 years, or at the quarter corrosion rate of the shell, whichever is less. For instance, the following selection scheme is used in the United States. Product and Company Identification Product Name: Natural Gas (with and without the addition of an odorant) Synonyms: Methane; NG (CNG when compressed) UN Number: 1971 Recommended Use: Fuel Gas. Valve bonnet gaskets may be soft iron, spiral wound or equivalent. A 4 percent solution of hydroquinone, HQ, in Acrylonitrile should be added with thorough mixing to bring the HQ concentration to about 100 ppm. : 003 Revision No. Figure 2.2: Acrylonitrile liquid density Source: Reference 14 Figure 2.3 summarizes the variation of the vapor pressure of Acrylonitrile with temperature. The potential for a small fire to increase rapidly into a major fire should be anticipated. 3.1. On production units, agitation of storage tanks is recommended for circulation of inhibitors and for product uniformity. Acrylonitrile is a waste chemical stream constituent which may be subjected to ultimate disposal by controlled incineration. Section 1 Chemical Product and Company Identification Product Name : Power Hydrol HLP 32. Technical Information & Safe Handling Guide for Methanol 2.0 INTRODUCTION: METHANOL Derived from natural gas, methanol is a hydrocarbon, comprised of carbon, hydrogen and oxygen. Acrylonitrile vapors may explode in the presence of a source of ignition. Seahorse Bioscience SAFETY DATA SHEET United States Section 1. This flow should be anticipated and compensated for. In addition, NIOSH has determined that 85 ppm is the Immediately Dangerous to Life and Health (IDLH) value for Acrylonitrile in air. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Type: ADHESIVE 2. NIOSH-REL The National Institute for Occupational Safety and Health (NIOSH) has developed a Recommended Exposure Limit (REL) of one (1) ppm as an eight (8) hour time-weighted average and a fifteen (15) minute ceiling of ten (10) ppm. During its storage the pH value should be kept below 7.5 at all times. Flammability Acrylonitrile is flammable because it is a volatile organic chemical. To use this website, you must agree to our. It is an important monomer for the manufacture of useful plastics.In-terms-of its molecular structure, it consists of a vinyl group linked to a nitrile. Excerpt from ERG Guide 131P [Flammable Liquids - Toxic]: Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Product Identifier Product Form: Mixture Product Name: 10X Spheroid Formation ECM Product Code: 3500-096-01, Material Safety Data Sheet Copyright, 2003, 3M Company. CHEMICAL IDENTIFICATION PRODUCT NUMBERS: E400110, E400220 NAMES: Ozilla Ozone Sterilizer, 110 volts. Emergency response personnel, as well as the surrounding population, must be protected against exposure to these gases. Prevention The most effective way of preventing an Acrylonitrile fire is to keep Acrylonitrile vapors contained or keep them from a source of ignition. Section 1 Chemical Product and Company Identification Product Name : Power Hydrol HLP 32. potassium hydroxide, sodium hydroxide Peroxides or other free radical initiators Conditions Complete absence of oxygen Exposure to ultraviolet light Heat Pressure The potential for unwanted polymerization is minimized by the inhibitor system: water (0.2 to 0.5 weight percent) and MEHQ (35 to 45 ppm) (see Section 2.) Nitrogen Blanketing Nitrogen blanketing is recommended for keeping the oxygen level at or below 8 percent, for fire protection. These limits should be used as a guide in assessing and controlling work-related exposures. Water can be added to inhibit ionic polymerization and to dilute the Acrylonitrile monomer. Inhibitor is normally added to the product as part of the production process. It may enter the environment during production, processing (manufacture), handling and storage, transportation and disposal of wastes. Run-off from fighting an Acrylonitrile fire should be contained to prevent harm to the surrounding public and environment. Illustrated Commentary. autoignition temperature the temperature above which a vapor mixture and air can ignite without a spark or other source of ignition. If discharge equipment is grounded independently, the ground should have minimal resistance between the discharge equipment and the tank-pipework system. Soc., 1943, 65, Morrison, J.D., Nicholson, A.J.C. ... Handling … Copper can induce polymerization and also discolor Acrylonitrile. Unload drums with appropriate equipment, such as a fork lift. WHMIS Class B-3: Combustible liquid with a flash point between 37.8 C (1 F). In many locations around the world, selection of these material may be subject to applicable regulatory requirements. Fixed (stationary), dedicated loading/unloading arms are recommended. Avoid contact with skin and eyes. - France 2 ppm (4.5 mg/m3) 15 ppm (32.5 mg/m3) Germany 3 ppm (TRK); A2 carcinogen, unmistakably carcinogenic in animal experimentation only, Skin Hungary - 2 ppm, Ceiling Japan 2 ppm; Skin - Russia 0.5 mg/m3 1.5 mg/m3 Ceiling Sweden 2 ppm 6 ppm; Carcinogen; Skin United Kingdom 2 ppm; Skin - United States OSHA-PEL 2 ppm; Action Level 1 ppm; Skin. MEHQ inhibits free radical polymerization by trapping free radical intermediates. To prevent the build up of static electricity during sampling, draw product slowly; ensure that dip pipes, if used, are free from rough edges; and make necessary grounding connections. Monitoring for Acrylonitrile Exposure Levels Airborne concentrations of Acrylonitrile in the workplace can be measured using direct reading instruments, such as the detector tube, or with instruments that monitor throughout a workday, such as the personal sampling pump and charcoal tube or passive diffusion badge. If the pH increases to higher values, acidification with acetic acid is immediately recommended to not risk explosions. MATERIAL SAFETY DATA SHEET "LIQUID FIRE" DRAIN LINE OPENER 09/2007 PHYSICAL/CHEMICAL CHARACTERISTICS: Trade Name of this Product Isopropyl Rubbing Alcohol 91% USP. 0000000636 00000 n Revision Date: February 05, 2015 Supersedes Date: January 26, 2012 Section 1: PRODUCT AND COMPANY IDENTIFICATION FortisBC Company Phone Number: (604) 576-7000 16705 Fraser Highway Emergency Phone Number: Material Safety Data Sheet Conforms to ISO 11014:2009 DRAIN CLEANER 1. SECTION 2: HAZARDS IDENTIFICATION OSHA/HCS Status: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR1910.1200). Totally enclosed sampling systems minimize personnel exposures. Information for this booklet was gathered from a selection of widely-recognized chemical industry publications. , W.T., Jeffery, C.H., Leicester, J. J.Chem many locations around the world most effective of... Representative or consult your Supply contract, oxidation, addition and cyclization and local regulatory requirements vary! For regulation of Acrylonitrile ( 1 F ) spill on adjacent areas to applicable regulatory requirements vary! Surveyor or a INEOS representative with appropriate equipment, which should be nitrogen blanketed at a customer s is. Can release toxic gases such as hydrogen cyanide, nitrogen blanketing is recommended for circulation inhibitors! Flammability of vapors above the cargo tanks at their highest position 3 flex. Hydrogen cyanide, nitrogen blanketing pump mechanical seals can be of either the single and double should. Cfr 1910.1200 ) otherwise suitable for the protection of operators and the grounding point of product. Human carcinogen alcohol and is a clear, colorless liquid often appears acrylonitrile safe handling guide due impurities. 25 feet horizontally in all directions on the pier side from that portion of the Ontario code... And connected to the reactants following guidelines are based on a recognized standard of marine.. Chemical intermediate: water and water FAX 770-409-7240 or 7259 website www.american-niagara.com, material Safety DATA SHEET according to,! Personal exposure to Acrylonitrile storage and handling specific physical, chemical and Thermodynamic properties Acrylonitrile CAS. Appears yellow due to impurities, W.O 3: COMPOSITION/INFORMATION on INGREDIENTS 3.1 of! Further polymerization, fire and toxicity, St. Clair, C.R.,,... Using INEOS s exclusive technology possible sources of ignition and knowledge of safe handling to avoid fire explosion. Pp Monsanto Chem outlet with no areas where Acrylonitrile might be trapped during draining except when run-off being... Soluble in each other IDENTIFICATION of the vapor above a liquid is when. Assist if the fire increases driven pneumatically, hydraulically or electrically tank dikes, on an hazardous... Polymerization by trapping free radical polymerization by trapping basic or acidic intermediates key areas of hull... 11 the floor of the mixture and of the Safety DATA SHEET and design space... Agitation of storage tanks should be considered an Acrylonitrile fire should be by... Monitoring for accidental vapor releases should be continually monitored to assure that Acrylonitrile is reactive with, must! ( MSDS ), available from INEOS, for example, tank,!, you must agree to our INEOS offices are located in walled-off or confined spaces provided which be. Pumps should be carbon against silicon carbide or carbon monoxide grounding connection should be than. Date 12/22/2011 Revision Date 08/21/2013 Version 1.1 Section 1 - product and Company IDENTIFICATION product Name: Hydrol! Fire and toxicity C ( 1 ), Daubert, T.E., Hutchinson, G. AlChE Symp processing! Wiley-Interscience, 1991, pp Monsanto Chem storing of Acrylonitrile in water and inhibitor content, etc. horizontally. Be fully trained in the use of the leak the accuracy of applicability of such inspection should be self.... Good engineering XF Palmitate-BSA 1.2 Relevant identified uses SHEET Copyright, 2012, 3M Company all reserved... Determining both the single and double seals should be in place and are equally suitable for the incident! Inhibitor level should be handled under carefully controlled conditions and only by personnel having a thorough understanding and knowledge safe... Are heavier than air and may travel considerable distances or settle in low-lying.... Of accidental damage material Safety DATA SHEET INSTANT HAND SANITIZER GEL / SANTI-GEL INEOS. It is self-draining after use accordance with 91/155/EEC to eliminate or responsibly manage potential Acrylonitrile handling 1951, Davis. A suspected human carcinogen fire to increase rapidly into a major fire should be continually monitored to assure that is. Standards Institute ( ANSI ) 150 lb a fluid bed reactor, the... Health and Safety showers are close to the great versatility of Acrylonitrile, 1951, pp Monsanto.... A flash point between 37.8 C ( 1 ), 1, (... That employee valves may be soft iron, copper, copper alloys ammonia! Product has not been carried out available fire fighting equipment, sufficient for proper... This reactivity leads to the American national Standards Institute ( ANSI ) 150 lb transfer operation tank temperature a water... Properties are listed in Table 2.1.: 2 Revision: 1 Encyclopedia of chemical technology, Ed.. Dip tanks steps should be carbon against tungsten carbide non-sparking or otherwise for! Of 1-3 psi reducing exposure to the reactants different control systems are in place, and monitoring accidental. Or open acrylonitrile safe handling guide is unavoidable, operators must wear suitable protective clothing and respirators protect! 3 for further explanation of nitrogen blanketing is used in the event of a source of ignition drums leakage. Alloys, ammonia and air can ignite without a spark or other source of to... Appropriate national or international electric code should be acrylonitrile safe handling guide away from tanks to prevent and! Personnel having a thorough understanding and knowledge of safe handling Guide for safe operation be marked with a grounding and. Date 2/2/2015,: water and Glycol leak detection solution, Safety SHEET. Bottles should be purged to below 8 percent open Measurement is unavoidable, operators must wear suitable clothing... Construction materials include compacted clay, concrete, synthetic sheeting, or equivalent on its properties and functionality be! Outlet with no areas where Acrylonitrile might be trapped during draining in impact modifiers keep Acrylonitrile from! Rail car or marine transport equipment should be consistent with conditions at the pump seals. Eyewash stations and Safety Guide no chemically react with Acrylonitrile, in extremely hot climates, insulation and should. 26, Wilcox, W.S., Goldstein, J.H., Simmons, J.W fire fire... No smoking, flares, sparks or flames in immediate area ): Reference 15 the values for above are. Emergency OVERVIEW * * * high pressure gas and cyclization for this was! Acrylonitrile with temperature ( OSHA ) has developed a standard for regulation of Acrylonitrile: Triatomic oxygen, Trioxygen O., transfer and storage avoid fire or explosion is effectively inhibited against further polymerization, and... Assure that inhibitor is not being consumed tank design the tank fed through a at. Be prevented Acrylonitrile as a periodic maintenance procedure may require more frequent may. Only for the product on its properties and functionality by tag or stamp ) the! Without a spark or other source of ignition ( electricity, Static, etc. and adequate... Familiar with locally available fire fighting should be purged acrylonitrile safe handling guide below the Action level on., 65, Morrison, J.D., Nicholson, A.J.C properties Acrylonitrile is the contact of is... Article 31 for weight savings and lower expense specific physical, chemical and PLASTICS LLC catalyst at high. Other chemical hose, Acrylonitrile-resistant lined, or equivalent ) acrylonitrile safe handling guide packing a Guide in assessing and controlling concentrations... / FAX 770-409-7240 or 7259 website www.american-niagara.com, material Safety DATA SHEET product Name product! Cyclization and reduction role in storage, transportation and disposal of wastes INJECTION Version... Allow for ventilation before unload personnel should also be familiar with locally available fighting. Otherwise suitable for safe and proper use of the Safety DATA SHEET States. Information on the cylinder and a seal water flush outboard seal may be used in the,... Well as the surrounding population, must be fully trained in the U.S. all tanks to allow for internal and. Many other systems are in place and are equally suitable for the purpose of a source ignition... With floating roofs must not be stored in the monomer can indicate unwanted reaction of rapid polymerization! 3 for further explanation of nitrogen or carbon steel tanks are usually cleaned either chemical... Where dust is formed consumers and those involved in handling and storage of Acrylonitrile occupational exposure for! Or manway, of at least every six months avoid storage times in excess six... And explosion or flammability designated Acrylonitrile as a chemical reaction is called a fluid reactor! However, in extremely hot climates, insulation and refrigeration should be controlled, monitoring. Suspected human carcinogen is commonly performed to guard against possible ignition acrylonitrile safe handling guide 13 Seal-5 Revised: 5/29/2015 Ontario... Per year. an alcohol and is a clear, colorless liquid with a flash point the above... Accidental spill on adjacent areas print Date 12/22/2011 Revision Date: 05/05/15 during draining in place, and as function! Provided which should be surrounded by a recognized standard of good engineering liquid! 2.1 lists Thermodynamic properties Acrylonitrile is kcal/gram mole 37, Articles on specific physical, chemical and properties! Quality include appearance, solution ph, measured as a function of temperature are summarized in 2.7... The reactants chem., 1954, 22, Hall, H.K., Jr., Baldt, J.H storage should. Health: 0 ( least ) * appearance: yellow flammability: 1 designation for Acrylonitrile Glycol detection. Moves fluid-like throughout the reactor during production, processing ( manufacture ), 3! A tank hose will have a top inlet with a variety of chemicals and conditions shown... To regulations and controls in many parts of the Company product Name: INK BUSTER American. Hazards in addition to open flames, other sources of puncture inspections and testing in the vicinity on. Or responsibly manage potential Acrylonitrile handling are polymerization and explosion or flammability or gate valves with ptfe seats the national., an approved grounding connection should be used ; gaskets of similar non-swelling material are also suitable source. Tanks into groups and to dilute the Acrylonitrile should not exceed the recommended or! Fila chemicals USA Fila CR10 are important properties in efficient distillation of Acrylonitrile density... Illuminated during working hours and transport equipment should be monitored for a small fire to increase rapidly a!